Trimethyl 4-(4-Chlorophenyl)-2-hydroxy-2-(2-methoxy-2-oxoethyl)-6-oxo-1,3,5-cyclohexanetricarboxylate
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چکیده
منابع مشابه
SYNTHESIS OF 8-HYDROXY-6-METHOXY- 3-UNDECYLISOCOUMARIN AND 2-HY DROXY - 4-METHOXY-6-(2-OXOTRIDECYL) BENZOIC ACID
Straightforward conversion of (+)-6,8-dimethoxy-3,4-dihydro-3- undecylisocoumarin (3) to the title isocoumarin was carried out. Hydrolytic ring opening of (3) afforded the hydroxy acid (4) which was immediately oxidized to keto acid (5) using chromic acid, Cyclodehydration of (5) afforded the 6,8- dimethoxy-3-undecylisocoumarin (6) which on selective demethylation of 8- methoxy group furni...
متن کاملsynthesis of 8-hydroxy-6-methoxy- 3-undecylisocoumarin and 2-hy droxy - 4-methoxy-6-(2-oxotridecyl) benzoic acid
straightforward conversion of (+)-6,8-dimethoxy-3,4-dihydro-3- undecylisocoumarin (3) to the title isocoumarin was carried out. hydrolytic ring opening of (3) afforded the hydroxy acid (4) which was immediately oxidized to keto acid (5) using chromic acid, cyclodehydration of (5) afforded the 6,8- dimethoxy-3-undecylisocoumarin (6) which on selective demethylation of 8- methoxy group furnished ...
متن کامل2-(4-Bromophenyl)-2-oxoethyl 4-methylbenzoate
The title compound, C(16)H(13)BrO(3), consists of a toluene ring and a bromo-benzene ring which are linked together by a 2-oxopropyl acetate group. The dihedral angle formed between the toluene and bromo-benzene rings is 80.70 (7)°. In the crystal, inter-molecular C-H⋯O hydrogen bonds link the mol-ecules into a three-dimensional network.
متن کامل2-(4-Chlorophenyl)-2-oxoethyl 4-methylbenzoate
In the title compound, C(16)H(13)ClO(3), the dihedral angle between the benzene rings is 80.74 (8)°. In the crystal, C-H⋯O hydrogen bonds link the mol-ecules to form C(11) chains propagating in [010].
متن کامل2-(4-Fluorophenyl)-2-oxoethyl 4-methoxybenzoate
In the title compound, C(16)H(13)FO(4), the dihedral angle between the benzene rings is 84.28 (8)°. In the crystal, C-H⋯F and C-H⋯O hydrogen bonds link the mol-ecules to form a three-dimensional network. The crystal structure is consolidated by C-H⋯π inter-actions and short F⋯F contacts [2.7748 (14) Å] also occur.
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ژورنال
عنوان ژورنال: Molbank
سال: 2003
ISSN: 1422-8599
DOI: 10.3390/m324